Incipient Metals: Functional Materials with a Unique Bonding Mechanism
نویسندگان
چکیده
منابع مشابه
Dichlorostannylene complexes of group 10 metals, a unique bonding mode stabilized by bridging 2-pyridyldiphenylphosphine ligands.
The reaction of tin dichloride with catalytically-relevant group 10 metal precursors [M(Cl)(X)(2-PyPPh(2))(2)] (M = Ni, Pd, Pt; 2-PyPPh(2) = 2-pyridyldiphenylphosphine; X = Cl, Me) provides easy access to unprecedented cationic dichlorostannylene complexes [M(X)(2-PyPPh(2))(2)(SnCl(2))](+) where the M-Sn bond is bridged by two head-to-head coordinated 2-PyPPh(2) ligands. The formation of such s...
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ژورنال
عنوان ژورنال: Advanced Materials
سال: 2018
ISSN: 0935-9648
DOI: 10.1002/adma.201803777